Hello @roberfp.
1) Basically, PREPREG is just isolation (no copper), CORE is COPPER-ISOLATION-COPPER. This video may help you:
How is a multilayer PCB made?2) Simply to say, microstrip is a way how you call tracks on TOP and BOTTOM layer, stripline is the way you call tracks build inside PCB. If you would like to know more, you can google for "stripline vs microstrip" as it is a little bit more complicated to explain into details.